Disinfection is an essential treatment component of greywater recycling system to ensure that treated greywater is fit for use. Among the disinfection options available for greywater are chlorine containing chemicals like sodium hypochlorite, chlorine dioxide, UV radiation, membrane filtration, and advanced oxidation processes involving use of ozone or hydrogen peroxide. Each of these has advantages in different circumstances, and in many cases a combination of these approaches is best for disinfecting greywater.
All disinfection systems shall be automated with alarms and automatic shut-off of the treated greywater supply in case of failure. Effective maintenance and a quality assurance system would minimise the risk of treatment failure. All chemicals used in the greywater recycling systems for the treatment and water testing purpose shall be used, handled and stored in accordance with the relevant regulations and guidelines issued by the Ministry of Manpower, National Environment Agency, and other government agencies.\
The site management shall also take all applicable measures to protect workers and other personnel from any hazard that is likely to endanger their safety and cause adverse health effects. One such measure is to ensure that chlorine-containing chemicals are stored separately with adequate segregation and measures to prevent accidental mixing with acidic chemicals.
Chlorination
Chlorine for disinfection of greywater has to be done carefully. The chlorine dose and contact time required to ensure adequate disinfection of greywater will depend on the characteristics of the greywater (e.g. pH, BOD and TSS), the chlorine demand (determined by the presence of organic matter, ammonia, iron and manganese) and the final uses of the treated greywater (e.g. whether a residual is required). Also, there can be problems in measuring free versus available chlorine in greywater due to the formation of chloramines following the reaction of chlorine with ammonia in the effluent. This means that no single figure for free or total chlorine can be specified for chlorine disinfection of greywater.
As with some other disinfectants, chlorine produces disinfection by-products in reaction with organic and inorganic substances usually present in greywater. The level of these by-products varies with the chlorine dose and the level of free chlorine in the greywater.
Due to the presence of organics and other substances in the greywater, the chlorine demand would vary, when chlorination is practised. Also, at high pH, chlorine will not be effective as a disinfectant. These factors, together with the contact time for chlorine, shall be considered while designing the treatment programme for greywater recycling systems. The treatment programme should ensure that disinfection is carried out effectively.
Also, chlorine is relatively ineffective at inactivating some pathogens, such as Cryptosporidium oocysts, and the residual chlorine can be toxic to sensitive organisms if it is released into the environment during final use of treated greywater. When this potential for toxicity must be reduced, de-chlorination may be required.
Ultraviolet radiation
Ultraviolet radiation is an effective disinfection process that does not produce by-products that may be toxic to humans or the receiving environment. UV dose is a product of UV intensity and exposure time and is expressed as milliwatt seconds per square centimetre (mW.s/cm2). UV achieves disinfection by initiating a photochemical reaction that damages the DNA molecule within micro-organisms, so that cell division and consequently multiplication can no longer occur. The amount of cell damage depends on the dose of UV energy absorbed by the micro-organisms and their resistance to UV.
UV disinfection is only effective with greywater that has low suspended solids, turbidity and colour. A chemical residual, such as chlorine, may be required after UV disinfection to limit bacterial re-growth within the distribution system.
Oxidation processes
There are many oxidation processes that can be used for treatment and disinfection of greywater, the more common of which use ozone, chlorine dioxide or hydrogen peroxide. The most commonly used process is ozonation. For indoor premises, the level of ozone should not exceed the guideline stated in the Singapore Standard 554.
A disadvantage of ozonation is that it produces small quantities of disinfection by-products that may be hazardous to human health when ingested or inhaled in sufficient quantities. In addition, ozone gas is extremely toxic so ozone generating facilities must be managed in accordance with appropriate workplace health and safety provisions. If ozone-treated greywater has a significant amount of residence time in pipes, it is also likely to require chlorine residual to prevent microbial re-growth.